Scientific revolution - part 3

Chemistry

Chemistry, and its antecedent alchemy, became an increasingly important aspect of scientific thought in the course of the 16th and 17th centuries. The importance of chemistry is indicated by the range of important scholars who actively engaged in chemical research. Among them were the astronomer Tycho Brahe, the chemical physician Paracelsus, Robert Boyle, Thomas Browne and Isaac Newton. Unlike the mechanical philosophy, the chemical philosophy stressed the active powers of matter, which alchemists frequently expressed in terms of vital or active principles—of spirits operating in nature.

Practical attempts to improve the refining of ores and their extraction to smelt metals was an important source of information for early chemists in the 16th century, among them Georg Agricola (1494–1555), who published his great work De re metallica in 1556. His work describes the highly developed and complex processes of mining metal ores, metal extraction and metallurgy of the time. His approach removed the mysticism associated with the subject, creating the practical base upon which others could build.

English chemist Robert Boyle (1627–1691) is considered to have refined the modern scientific method for alchemy and to have separated chemistry further from alchemy. Although his research clearly has its roots in the alchemical tradition, Boyle is largely regarded today as the first modern chemist, and therefore one of the founders of modern chemistry, and one of the pioneers of modern experimental scientific method. Although Boyle was not the original discover, he is best known for Boyle's law, which he presented in 1662: the law describes the inversely proportional relationship between the absolute pressure and volume of a gas, if the temperature is kept constant within a closed system.

Boyle is also credited for his landmark publication The Sceptical Chymist in 1661, which is seen as a cornerstone book in the field of chemistry. In the work, Boyle presents his hypothesis that every phenomenon was the result of collisions of particles in motion. Boyle appealed to chemists to experiment and asserted that experiments denied the limiting of chemical elements to only the classic four: earth, fire, air, and water. He also pleaded that chemistry should cease to be subservient to medicine or to alchemy, and rise to the status of a science. Importantly, he advocated a rigorous approach to scientific experiment: he believed all theories must be proved experimentally before being regarded as true. The work contains some of the earliest modern ideas of atoms, molecules, and chemical reaction, and marks the beginning of the history of modern chemistry.

Optics

Important work was done in the field of optics. Johannes Kepler published Astronomiae Pars Optica (The Optical Part of Astronomy) in 1604. In it, he described the inverse-square law governing the intensity of light, reflection by flat and curved mirrors, and principles of pinhole cameras, as well as the astronomical implications of optics such as parallax and the apparent sizes of heavenly bodies. Astronomiae Pars Optica is generally recognized as the foundation of modern optics (though the law of refraction is conspicuously absent).

Willebrord Snellius (1580–1626) found the mathematical law of refraction, now known as Snell's law, in 1621. Subsequently René Descartes (1596–1650) showed, by using geometric construction and the law of refraction (also known as Descartes' law), that the angular radius of a rainbow is 42° (i.e. the angle subtended at the eye by the edge of the rainbow and the rainbow's centre is 42°). He also independently discovered the law of reflection, and his essay on optics was the first published mention of this law.

Christiaan Huygens (1629–1695) wrote several works in the area of optics. These included the Opera reliqua (also known as Christiani Hugenii Zuilichemii, dum viveret Zelhemii toparchae, opuscula posthuma) and the Traité de la lumière.

Isaac Newton investigated the refraction of light, demonstrating that a prism could decompose white light into a spectrum of colours, and that a lens and a second prism could recompose the multicoloured spectrum into white light. He also showed that the coloured light does not change its properties by separating out a coloured beam and shining it on various objects. Newton noted that regardless of whether it was reflected or scattered or transmitted, it stayed the same colour. Thus, he observed that colour is the result of objects interacting with already-coloured light rather than objects generating the colour themselves. This is known as Newton's theory of colour. From this work he concluded that any refracting telescope would suffer from the dispersion of light into colours. The interest of the Royal Societyencouraged him to publish his notes On Colour (later expanded into Opticks). Newton argued that light is composed of particles or corpuscles and were refracted by accelerating toward the denser medium, but he had to associate them with waves to explain the diffraction of light.

In his Hypothesis of Light of 1675, Newton posited the existence of the ether to transmit forces between particles. In 1704, Newton published Opticks, in which he expounded his corpuscular theory of light. He considered light to be made up of extremely subtle corpuscles, that ordinary matter was made of grosser corpuscles and speculated that through a kind of alchemical transmutation "Are not gross Bodies and Light convertible into one another, ...and may not Bodies receive much of their Activity from the Particles of Light which enter their Composition?"

Electricity

Dr. William Gilbert, in De Magnete, invented the New Latin word electricus from ἤλεκτρον (elektron), the Greek word for "amber". Gilbert undertook a number of careful electrical experiments, in the course of which he discovered that many substances other than amber, such as sulphur, wax, glass, etc. were capable of manifesting electrical properties. Gilbert also discovered that a heated body lost its electricity and that moisture prevented the electrification of all bodies, due to the now well-known fact that moisture impaired the insulation of such bodies. He also noticed that electrified substances attracted all other substances indiscriminately, whereas a magnet only attracted iron. The many discoveries of this nature earned for Gilbert the title of founder of the electrical science. By investigating the forces on a light metallic needle, balanced on a point, he extended the list of electric bodies, and found also that many substances, including metals and natural magnets, showed no attractive forces when rubbed. He noticed that dry weather with north or east wind was the most favourable atmospheric condition for exhibiting electric phenomena—an observation liable to misconception until the difference between conductor and insulator was understood.

Robert Boyle also worked frequently at the new science of electricity, and added several substances to Gilbert's list of electrics. He left a detailed account of his researches under the title of Experiments on the Origin of Electricity. Boyle, in 1675, stated that electric attraction and repulsion can act across a vacuum. One of his important discoveries was that electrified bodies in a vacuum would attract light substances, this indicating that the electrical effect did not depend upon the air as a medium. He also added resin to the then known list of electrics.

This was followed in 1660 by Otto von Guericke, who invented an early electrostatic generator. By the end of the 17th Century, researchers had developed practical means of generating electricity by friction with an electrostatic generator, but the development of electrostatic machines did not begin in earnest until the 18th century, when they became fundamental instruments in the studies about the new science of electricity. The first usage of the word electricity is ascribed to Sir Thomas Browne in his 1646 work, Pseudodoxia Epidemica. In 1729 Stephen Gray (1666–1736) demonstrated that electricity could be "transmitted" through metal filaments.